Self-assembly of heteroleptic dinuclear silver(i) complexes bridged by bis(diphenylphosphino)ethyne
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چکیده
منابع مشابه
Dinuclear dialkoxo-bridged cyclopentadienylsiloxo titanium complexes.
The dinuclear dialkoxo-bridged complexes [(TiCl)(2)(mu-O(2)L)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] (O(2)L = 1,2-O(2)C(2)H(4), 1,2-O(2)C(6)H(4), 1,2-(OCH(2))(2)C(6)H(4), O(2)SiPh(2)) were obtained by reaction of [(TiCl(2))(2)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] () with the corresponding dilithium salt () or diol (, , ). Alkylation of and with ClRMg afforded [(TiR)(2)(mu-O(2)L)(mu-{(eta(5)...
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Crystals of trans-Pt₂(μ-X)₂X₂(CO)₂ (X = Br, I) have been grown and their molecular and crystalline structures have been solved by X-ray diffraction methods. In both cases the dinuclear molecules are bent, with a bending angle of 164.6° and 156.5° for the bromide and the iodide, respectively. While the structure of the bromo-derivative is reported here for the first time, a modification of trans...
متن کاملFour-electron reduction of dioxygen catalysed by dinuclear cobalt complexes bridged by bis(terpyridyl)anthracene.
Dinuclear cobalt-1,10-phenanthroline (1) and 2,2'-bipyridine (2) complexes bridged by 1,8-bis(2,2':6',2''-terpyrid-4'-yl)anthracene (btpyan) were prepared. Both of the complexes selectively catalysed the electrochemical four-electron reduction of dioxygen to H2O without the generation of H2O2 as a two-electron reduction product.
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2018
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c7dt03923a